Category Polymers

What is stubble burning?

The air quality in Delhi and other parts of north India hit a hazardous level this month. Levels of dangerous particles in the air – known as PM2.5 – were over 10 times the safe limits in the capital. The air quality index (AQI) crossed an all-time high of 1,000 in some places on November 3. As per data, the AQI between 0 and 50 is considered safe, 51-100 satisfactory, 101-200 moderate, 201-300 poor. At 301-400 it’ considered very poor and 401-500 falls in the severe category. When the AQI crosses the 500 mark, it falls into the emergency category.

The odd-even rule, a car rationing scheme, came into effect on November 4. (As per rule, cars with odd numbers will be allowed to run on odd days such as Nov 5, 7 etc., and cars with even numbers will be allowed on even days such as Nov 6, 8, etc.). Delhi Chief Minister Arvind Kejriwal blamed crop burning in Haryana and Punjab for increased pollution levels in the capital during winter.

Air pollution is a year-round problem in Delhi due to vehicular and industrial emission, but the impact is felt more during the winter months. The capital’s low air quality during the winter is attributed to its geography, low wind speed and stubble burning by farmers in the neighbouring States of Punjab and Haryana. These farmers have come under fire for taking the air quality to a dangerous level.

Stubble burning is the practice of removing crop residue from fields post-harvest by setting fire to it. This usually happens during October and November (autumn months), as the farmers begin to prepare the field for sowing winter crops – especially wheat.

As the southwest monsoon retreats, it sets off northwesterly winds, which carry the smoke from the burning of stubble towards Delhi and other northern regions.

According to the agriculture ministry, 23 million tonnes of paddy straw is burnt in Punjab, Haryana and UP every year.

 

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Are there schools that accept plastic as fees?

           Does your school accept plastic as fees? There is a unique school in the outskirts of Guwahati, Assam which does. If a student brings 25 pieces of plastic, it is accepted as fees in Akshar School. The plastic waste that they bring is recycled to make eco-friendly bricks that can be used for construction.

          When Parmita Sarma and Mazin Mukhtar started this school in June 2016, their aim was to provide free education to poor kids. Their plan took a slight twist when they saw the villagers making bonfires of plastic to beat the cold.

           They wanted to educate the villagers about the harmful effects of plastic and hence modified the fee structure from having no fees to plastic waste as fees. A practical lesson in recycling! The school provides socially and environmentally relevant education.

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Which is the first Indian state to ban disposable plastic bags?

           Sikkim, a tiny state in the foothills of the Himalayas is famous not only for its natural beauty and biodiversity, but also for its eco-friendly stands.

           In 1998, Sikkim became the first Indian state to ban disposable plastic bags. They were eliminated from both rural and urban areas and labelled as hazardous. 2016 is an environmentally important year for Sikkim as the state took two landmark decisions. The first was to ban packaged drinking water in government offices and at government events.

           The state has also banned the use of disposable styro-foam and thermocol plates and cutlery.

           It now targets single-use plastic bottles.

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Why is Modbury important?

            Modbury was a not so famous village in England which came to the spotlight in 2007. It secured a place in history with a life-changing decision to ban plastic carry bags forever. Thanks to the efforts of Rebecca Hosking, Modbury is the world’s first ever plastic bag free zone.

           Rebecca screened her documentary Message in the Waves for the local shop owners of her hometown who were stunned to see the disastrous effect of plastic on marine environment. Crushed by the impact of the film, the shopkeepers decided to stop giving plastic bags. After a successful trial run for six months, plastic bags permanently disappeared from Modbury. They now use biodegradable cornstarch bags and reusable cotton, jute or paper bags.

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What are the advantages of bioplastics?

            The production of bioplastics is eco-friendly, as they use renewable sources rather than the non-renewable sources, thus saving a lot of energy. They also make use of agricultural waste material. It produces less non-biodegradable waste than other plastics. It is therefore less contaminating.

            They do not change the scent or taste of the packed food. No harmful substance would leach out of bioplastics and they do not use additives that may affect health like phthalates and bisphenol-A. They give out less greenhouse gases as well. They are decomposable and cause no harm while blending with soil.

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Do we have an eco-friendly alternative to plastics?

           It is ironic that the food items that last less than a week are packed using plastics that stay intact for centuries. Scientists had worked hard to find eco-friendly alternatives and by the 1990s, bioplastic was brought into the markets.

           Plastics are derived from non-renewable sources like petroleum or natural gas. Unlike them, bioplastics are made from renewable sources of biomass like bacteria, food waste, vegetable oils and corn starch. Bioplastics are mainly used for packaging and making disposable cutlery, straws and bowls.

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Why is the documentary Albatross important?

           The documentary Albatross took shape in 2008 after a discussion between Chris Jordan and his friend Manuel Maqueda about the issue of ocean plastic pollution. They studied about young albatrosses dying of indigestion after eating plastic. They recorded what they witnessed in Midway Island in the north of the Pacific Ocean. They worked for more than four hundred hours and the footages were made into a film showcasing the plight of the species. The documentary was released in 2017.

           Albatross projected the devastating effect of plastic on marine ecosystems. It was found that nine in ten birds have traces of plastic debris in them. It helped in understanding the drawbacks of our lifestyle and the severity of the problem.

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Are animals harmed by polymers?

           People in the south coast of Spain woke up to a huge dead sperm whale on a March morning in 2013. After careful examination, it was found out that the whale had died of severe indigestion. About 17 kilograms of plastic was found inside its body which had led to its death.

           This sperm whale is not the first animal to die because of our waste and it is not the last. Plastic poses a threat to the animals around us. Have you observed cows and buffaloes eating plastic from the garbage? These poor animals mistake plastic for food and end up eating it. This is known as food imitation; it leads to severe indigestion and they eventually die.

           Plastic has been found in the bellies of many types of fish and stray animals.

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Is the packaging of Chips eco-friendly?

          Most of us love packaged chips. Let us now take a look at the journey of its packaging. These attractive packages are made of a kind of polypropylene known as BOPP.

          Lead and cadmium-based additives are used in the production of BOPP. This packaging material catches fire easily. To reduce its inflammability, some flame retardants are also used.

          The burning of this packaging material releases harmful substances like formaldehyde which is capable of causing respiratory diseases. Toxic substances are also released while this material is recycled. Workers in the recycling plants have often reported to suffer from health issues like headaches, asthma, skin and nasal irritation due to their exposure to harmful chemicals.

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How does polyurethane affect our environment?

           Commonly known as PU, polyurethane is a polymer that is used to make cushions and mattresses. It is also used as enamel for paints. Though it provides us a comfortable night’s sleep without disturbances, it disturbs our environment. Sad, but true.

           PU cannot be recycled. Sometimes it is burned or simply dumped in landfills. Toxic substances like dioxins are released when PU is burned. You already know what this toxic chemical can do to us. Besides dioxins, other harmful substances like isocyanides and hydrogen cyanides are also produced.

          When PU degrades, it gives out chlorofluorocarbon (CFC) that depletes the ozone layer.

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How safe are our feeding bottles?

           Most babies are fed using feeding bottles. A plastic called polycarbonate is used to make feeding bottles because it is strong, durable and heat resistant to an extent. It can be sterilized easily and would not soak up odours. When it was first introduced, it was commonly accepted as a suitable substitute for glass and ceramic. Polycarbonate is preferred for making the inner linings of food containers and reusable plastic bottles as well.

           Though polycarbonate is a preferred material, it is not essentially safe. A harmful substance known as bisphenol-A leaches out of the polymer and gets mixed with food. This chemical can cause health issues. It changes the level of oestrogen in our bodies.

How bad are polyethylene bags for us?

           Polyethylene bags have multiple applications in our daily life. Though we use polyethylene products at least five times a day, they are not entirely safe.

           Lead and cadmium are used as additives in polyethylene. These metals are toxic and are known to leach out.

           Lead affects the nervous system; it is capable of causing unconsciousness, heart attacks, respiratory diseases and even death.

           Cadmium affects the cells and tissues of the kidneys and causes inflammation. It can also lead to diabetes. If these metals leach into the soil, it will result in soil and groundwater contamination.

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Which polymer is used to make wetsuits?

           Do you enjoy watching water sports like scuba diving or river rafting? If you do, you should know about neoprene, the polymer used to make wetsuits.

           Neoprene is a polymer made out of chloroprene monomers and has a wide variety of uses. This polymer shows good resistance to wear and tear and can be used in any weather. It is thermally stable and also resists heat and flames. Neoprene is buoyant; it has a tendency to remain afloat in water. It is highly flexible and can be stretched out easily. It is therefore used to make wetsuits.

           Neoprene is not a very expensive material and is used to make a range of other products like safety equipment such as gloves, laptop sleeves, knee and elbow supports, conveyor belts and children’s toys.

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How is zylon connected with Formula One racing?

            Zylon is a thermoset fibre that was developed in the 1980s. How would this polymer have connection with Formula One racing, the highest class of single seater auto racing?

           Zylon is one of the strongest man-made organic fibres. In fact, it is ten times stronger than steel. This polymer shows high flame resistance and would remain unaffected by most of the chemicals. It is therefore used to make Formula One racing cars.

           Zylon is used to attach the wheels of race cars used in Formula One to the chassis that is the framework of the vehicle. This prevents the wheel from falling into a crowded area, in case of an accident. The driver’s cockpit is also covered with special panels made of zylon. Nowadays, the helmets used in the race are also lined with zylon to reduce hazardous injuries.

           Zylon has other application too; it is used to make sports equipment like tennis racquets and table tennis blades. It also has some medical applications and is a preferred fibre in the manufacture of high altitude balloons. However, zylon is very expensive and is used only in highly demanding applications.

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Do solar cooking stoves and nail polish have something in common?

           You would be thinking that it is ridiculous to ask something like this. But, solar cooking stoves and nail polish have something in common- a polymer called Mylar.

           Mylar is a special type of stretched polyester generally known as BoPET. It is also known as Melinax and Hostaphan. Don’t be confused with too many names. It is made of polyethylene terphtalate (PET) monomers. It is transparent and chemically stable. It also provides good electrical insulation.

           Mylar is used for making packaging and lids for food products. It is also used as a covering over paper or clothing. This coating gives a shiny surface and a protective coating. It is used in a range of other products like the diaphragms of headphones.

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Why is Teflon used to make non-stick cookware?

           When you pour the dosa batter on a non-stick pan, the flour is sticky. But you can easily take out the dosa from the pan with a wooden spatula once it’s cooked. You don’t have to smear the pan with oil like the traditional ones. Wonder why? This would not be possible if not for the Teflon coating in the pans.

          Teflon does not melt easily. It has a high melting point and is also stable at very low temperatures. Teflon is extremely resistant to corrosion. It cannot be dissolved by most of the materials. In addition to this, it is very slippery and has high resistance corrosive chemicals. Therefore, Teflon provides a perfect coating material for cooking utensils that resists heat, friction and wear and tear. Teflon is also used widely in carpets, wall coverings, paints and as weatherproofing on outdoor signs.

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What is the chemical name of Teflon?

           Teflon is familiar to all of us from the advertisements of non-stick cookware and paints. But, Teflon is just the brand name. Polytetrafluoroethylene is the chemical name of Teflon. Quite a mouthful, right?

           Teflon is a compound made of tetrafluoroethylene monomers. The discovery of Teflon was not deliberate. A young scientist named Roy Plunkett who worked at Du Pont accidentally made Teflon while he was working on a refrigerant compound. He combined hydrochloric acid with tetrafluoroethylene to obtain a new compound.

           The gas formed in the reaction cooled down and transformed to a white powder overnight forming the new material – Teflon.

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Are there other fibres like kevlar?

            Kevlar belongs to the aramid family of fibres. So is twaron. Twaron shares many similarities with kevlar. It has a high tensile strength and shows great thermal stability just like kevlar. Twaron neither burns, nor melts. It also shows high resistance to chemical substances.

           Twaron was invented by a Dutch company named AKZO in the 1970s. But, it was not commercially produced until 1986, because of financial troubles. When it was first produced, twaron was called ‘fibreX’. Now, a company called Teijin produces twaron.

           Twaron too is used for making bulletproof body armour. It is also used to make optical fibre cables and substitutes for asbestos.

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How is melamine made?

           Do you have shiny, plastic cookware and plates in your kitchen? Most of these plates are made of melamine.

           Melamine is an organic compound which is mostly made of nitrogen. It is used to make a lot of industrial products like dinnerware, adhesives, glues, coatings and flame retardants.

           These days, urea is used as a starting material for the production of melamine. It can also be made from dicyandiamide or hydrogen cyanide. Urea is broken down and reacted to form melamine-formaldehyde resins.

           This can be moulded into different shapes forming dishes, handles, containers and so on.

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Who discovered Kevlar?

           Nylon is not the only revolutionary material that took birth in Du Pont. Kevlar too was developed in the laboratories of Du Pont. This time, they were trying to manufacture a stronger tyre and during her efforts, Stephanie Kwolek accidentally discovered Kevlar.

           Kevlar is used to make a range of products. It is used to make the inner lining of bicycle tyres, as Kevlar lining helps the tyres to last longer and avoid being punctured. It also has a variety of applications in sports and musical instruments. Nike was the first company to use Kevlar to make sports shoes. They were followed by several others including Adidas.

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Which polymer is commonly used to make bulletproof vests?

           There are metals that can resist bullets. But it would be difficult to carry bulletproof vests made of metals. The more convenient option is a lighter, strong fibre which will prevent the bullets from hitting your body and easy to wear at the same time. And that is why Kevlar is used for this purpose.

           Kevlar is one of the strongest materials on earth; when it is woven into fabric, it is five times stronger than steel. It can even resist knives. Kevlar has a strong ring-like structure and can resist high temperatures. It is used for making many types of body armour.

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How did nylon get its name?

            There are so many stories about the naming of nylon. A popular one goes like this: the polymer was named after two cities- New York and London. However, this is not true.

            The chemists of Du Pont had a tough time naming the new polymer Wallace discovered. Names like Duparooh -that honoured the company- and Wacara – that honoured Wallace- were suggested, but never really got an approval. After lengthy discussions, it was decided to name the polymer by adding the suffix -on, just as in cotton and rayon. The name ‘nuron’ was suggested and it got some approval. But, this name would probably be confused for a nerve tonic and was later modified to ‘nylon’.

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How is nylon 6 different from nylon 66?

           Both nylon 6 and nylon 66 are durable polymers. Their properties differ based on how the monomers are bonded.

           Monomers of caprolactam from nylon 6.  The monomers have 6 carbon atoms each. On the other hand, nylon 66 has two types of monomers – hexamethylenediamine and adipic acid. The repeating units have twelve carbon atoms. Nylon 6 is formed through a complex reaction called ring opening polymerization, while nylon 66 is formed through condensation polymerization.

           Nylon 6 has high strength and is very flexible. So, it is used to make things like gears, ropes, bearings and other parts of cars. Nylon 66 is rigid and is also resistant to heat and chemicals. Therefore, it is used in the textile industry to make garments and carpets.

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Were Nylon riots real?

           Would you believe it if someone tells you that there were riots in the name of a polymer? Well, be ready for surprises. Nylon riots were real! It happened in the US after the Second World War.

           Du Pont started making nylon stockings towards the end of the 1930s which drove American women crazy. Stockings were highly sought-after hosiery. Around four million stockings were sold in a day. During the war years, the silk export from Japan ceased and there was a shortage of nylon, as it was used to make war materials like parachutes and tents. Nylon stockings were produced no more. This created a shortage. It was so fashionable; black markets sold a few at high prices and many women resorted to paint their legs like transparent nylon stockings!

           After the war, nylon stockings reappeared in the markets. Hundreds of women lined up in the stores to get hold of limited nylon stockings. The shortage of stockings led to a series of disturbances in the US that occasionally broke into fights. Women flooded the stores knocking down shelves, and fighting hammer and tongs for the limited stock. The situation became terrible in Pittsburgh when 40,000 women lined up for 13,000 pairs of stockings.

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Which was the first successful nylon product?

           Can you name some products made of nylon? Apart from toothbrushes, a range of other products like fishing nets, fabrics, stockings, machine screws, gears, ropes, parachutes, tents, wind cheaters, hammocks, seat belts and sleeping bags use nylon.

           Stockings were the first successful product made of nylon. There was a craze for nylon stockings in the World War II era.

           Nylon is strong, light, elastic and lustrous. It is easy to wash and while washing, nylon does not stretch or shrink. It retains shape and dries quickly. Because of these reasons, nylon is usually preferred to make garments.

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Why is Wallace Carothers associated with nylon?

          Nylon would not be possible if not for a company named Du Pont and a scientist called Wallace Carothers. Remember Staudinger, the father of polymer chemistry? His research sparked the interest of chemists and paved way to more and more discoveries in polymers.

          Many chemical companies worked day and night to form new fibres that would create a revolution in the market. Du Pont was one among them. This American company worked to explore the commercial applications of polymers. Wallace Carothers joined Du Pont around the same time.

          Wallace could create tiny fibres in a test tube when he experimented with amine, hexamethylenediamine and adipic acid. But, the presence of water restricted the formation of long fibres. He tried removing water obtained in the reaction and guess what? He could make long fibres through a process called cold drawing. Thus, a new polymer took birth and was named nylon. This happened in the 1930s.

          Nylon was brought into the market in the 1940s. A crisis of natural fibres came along with other hardships of World War II. Chemists tried to develop a new fabric that could provide an alternative for natural clothing. Rayon was already discovered. Nylon too provided a cheap alternative and became a huge success in the market.

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Which polymer is used to make the bristles of a toothbrush?

           All of you use your toothbrush at least once a day. But, have you ever thought about the polymer used to make the bristles that clean your teeth every day?

           The bristles of a toothbrush are made of nylon. Nylon is a thermoplastic with a silky texture. It is a polyamide with a backbone made of amide monomers. Because of the hydrogen bonding between the monomers, nylon’s backbone is symmetrical.

           Nylon is resistant to biological and chemical agents. Imagine what would happen to your toothbrush if it reacted with saliva. It also resists abrasion to an extent; it won’t wear off due to rubbing. However, nylon degrades in the presence of UV light.

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Why is bakelite a material of thousand uses?

           Bakelite is a thermosetting plastic which shows high resistance to heat, electricity and chemical agents. It can be easily moulded into any shape and dyed into any colour. It is widely used to make insulating bushes, sockets for electric bulbs and other non-conducting parts of electrical appliances because of the electrical insulation it provides.

           It is used to make scores of products like clocks, radios, telephones, kitchenware, tableware, jewellery boxes, pipes, buttons, cameras, lamps, chess sets, billiard balls, and jewellery. Moreover, it is cheap and affordable. No wonder, it is called a material of thousand uses.

           Bakelite changed the trends in fashion too. Bakelite jewellery was highly sought-after in the 1920s as it offered an affordable and attractive replacement for other materials. It also played a role in World War I and II as it was used to make a lot of war materials.

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Who discovered the first synthetic plastic?

           Leo Baekeland started working with polymers to make money and he did make a lot of money, even before he discovered the first synthetic plastic. By then, he had already developed Velox photographic film, which made him rich.

           He later devoted his efforts to develop a substitute for shellac, a resin obtained from the shells of Asian lac beetles.

           After a lot of trials and errors, he finally succeeded in making a resin from phenol and formaldehyde, thus making the first ever synthetic plastic. It was cheaper than celluloid and had better properties. This thermosetting material could be easily moulded into different shapes as well. He called this substance ‘bakelite’.

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How did celluloid create history?

           Apart from resembling ivory, celluloid has other amazing properties as well. Celluloid is a permanent, hard solid at normal temperatures and when heated, it becomes soft and could be moulded or rolled into sheets. Because of these, it was used to make a wide range of products.

           By the 1880s, celluloid was used as a substitute for linen. It was used to make detachable collars and cuffs for men’s clothing. Photography wouldn’t have been possible if not for celluloid. 1n1882, John H. Stevens discovered that celluloid could be diluted using amyl acetate. He was working as a chemist at the Celluloid Manufacturing Company then.

           Diluting celluloid produced a clear, flexible film. Researchers like Henry Reichenbach of the Eastman Kodak Company further processed it into film for still photography. It was later used to make motion pictures.

           These films were inflammable and would discolour with age. But they remained the medium for motion pictures till the invention of cellulose-acetate safety film in the 930s.

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How is billiards connected to the invention of celluloid?

           Billiards was a fashionable sport in Britain during the Victorian era. Many of the rich people used fine billiard balls crafted out of ivory to flaunt their wealth. The game was a status symbol!

           A billiard ball has to have certain physical properties. It has to rebound properly and has to be of a certain density. Ivory was the best material for that. To make fine ivory balls, elephants across Asia and Africa were hunted down, which affected the species. The shortage of ivory increased as the number of elephants went down. This created a crisis; finely crafted billiard balls became a rarity.

           People soon began their search for a worthy substitute for ivory. In fact, a billiard-ball manufacturer from New York offered 10,000 dollars to the person who could create one. John Wesley Hyatt won the prize. He made celluloid, a semi-synthetic polymer by modifying cellulose. Alexander Parkes was the one who managed to produce the first material that resembled ivory. He made a substance called Parkesine, but it was not a commercial success.

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What are the benefits of using biopolymers?

           All polymers that are obtained from nature are known as biopolymers and they have several features that are eco-friendly. There are also man-made biopolymers that retain the properties of natural biopolymers. Biopolymers are renewable and sustainable.

           Biopolymers reduce the amount of carbon dioxide in the atmosphere. They are biodegradable; they can be broken down to carbon dioxide and water by microorganisms. Most of them are compostable as well. Thus, the chances of them polluting the environment are very less. Due to this, they are produced in large quantities and used for the production of plastics.

           Based on their structure, biopolymers can be classified into three – long nucleotide polymers called polynucleotides, short polymers of amino acids called polypeptides and linear chains of carbohydrates called polysaccharides.

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Who invented erasers?

           Before the discovery of erasers, wet bread crumbs were used widely for erasing. Imagine going to school with a packet of wet bread-crumbs. It would be funny.

          Edward Nairne, a British engineer once made a mistake while writing. He accidentally took a piece of rubber instead of bread crumbs to erase it and guess what? Rubber proved to be a better eraser. Thanks to Nairne’s mistake our school life has become easier. Every time you rub out your mistakes without a trace, just remember that your eraser was an accidental discovery.

           Joseph Priestley was the first one to discover the erasing properties of rubber, but Edward Nairne was the first to develop and market it.

            An eraser gets its common name ‘rubber’ from the rubbing action. It works chemically, pretty much like a sticky magnet. When it is rubbed over the writing, the graphite particles stick to the rubber, making erasing possible.

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Why is rubber used to make tyres?

           Rubber is the most preferred material to make tyres. It is an elastic polymer formed by the addition of isoprene monomers. When stretched, the monomer chains arrange themselves in a linear fashion.

           Rubber does not transfer heat. It is flexible and easy to mould into any shape. It has a greater friction as well. These qualities are desirable for tyres. In addition to this, it can be strengthened using additives that would make it strong, flexible and durable.

           Rubber melts at temperatures above 180 degrees celsius. Some of you might have visited rubber plantations. Have you ever smelled rubber while it is being made into sheets? It produces a severe bad odour while it is being processed. This is because of the production of hydrogen sulphide gas due to several chemical reactions.

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Who was the first person to vulcanize rubber?

           Have you heard of Goodyear tyres? Goodyear is a leading tyre manufacturer in the world. This American company was named so to commemorate Charles Goodyear, an American chemist and manufacturing engineer, the man who found out that rubber could be strengthened by the process of vulcanization.

           Before vulcanization was discovered, people found it difficult to make useful products out of rubber. Rubber would get sticky at high temperatures and harden in cold climates. Goodyear accidentally dropped a piece of rubber in sulphur and he discovered that it became more stable and flexible afterwards due to some chemical change. It had more strength than before. Since then, rubber is treated with sulphur to enhance its desirable properties and this chemical treatment is known as vulcanization.

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Which are the products made of rubber?

           How would you erase the mistakes that you make while writing with a pencil if not with an eraser? Erasers are made of rubber. This sticky, white substance obtained from the rubber tree is modified and made into several useful products.

           All the tyres of your cars, bikes and bicycles are made of rubber. The soles of your shoes, slippers, and swimsuits, swimming caps, collars of pet animals, boots, balls, gloves and seals are rubber in different forms.

           Birthday celebrations are incomplete without balloons, and guess what? Most of the balloons are made of rubber. The floating tubes that you play with in the swimming pool, rubber bands, mouse mats of computers, airbags… well, the list is endless! Look at the ducting of your cars, refrigerator or washing machine. All of that is rubber. Needless to say, rubber is an important polymer.

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How are microorganisms related to the process of polymerization?

          There are millions and millions of microorganisms around us which thrive in a variety of conditions. Some of these microorganisms play a part in the synthesis of polymers. Wonder how?

           Some microorganisms can live in extreme conditions. There are some thermal resistant bacteria that can withstand temperatures as high as 350 degrees Celsius and they are used in chain growth polymerization. It is a mechanism of polymerization in which monomers get added to a growing polymer chain. Some of these microorganisms are also used in the production of medicines.

           Apart from this, there are millions of tiny creatures in the sea that sink into the seabed when they die. Calcium carbonate is a common inorganic substance found in organisms that do not easily decompose. It piles up in the seabed and forms huge deposits of chalk and lime with the passing of time which is later used for making useful polymers like plastic and polyvinyl chloride.

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Is cartilage a polymer?

               Cartilage is a soft, yet firm tissue which performs some important functions in our body. It’s a flexible tissue found in the joints that connects bones. It also helps in the formation of bones. Cartilage too is a polymer.

               Cartilage is a protein made of amino acids. It is not only present in human beings, but also in other animals and some fishes. A fish with cartilage is commonly known as cartilaginous fish. Cartilage is tough, flexible and provides enough structural support.

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Were roads named after polymers?

          It will be ridiculous to name a road after polypropylene or polystyrene. But there is an important route in world history that was named after a polymer. Remember the Silk Road?

          The Silk Road is an ancient trade route that connects Asia and the Mediterranean Sea. It is named so because silk from China was a major article of trade then. As we all know, silk is a polymer which is used for making fine clothing. But, that is not the only use of silk.

           Silk is also used for making other products like sleeping bags, surgical sutures and bedding. Till some time ago, it was even used to make parachutes. Nylon was synthesized as an alternative for silk, but it does not possess all of its qualities.

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Can we wear polymers?

          We all might have worn clothes made of cotton, wool and silk at one point or the other. Most of us must have used belts, shoes and wallets made of leather. By now, we know that all these are polymers.

          Wool is made of fur obtained from different animals like sheep, llamas, angora rabbits and even foxes. Wool is used to make a range of clothing like socks, gloves and sweaters. It is one of the first materials used by Man to make clothing. Fur is made of a protein called keratin. Fur clothing is highly fashionable now.

          Leather, as discussed earlier, is obtained from the skin of animals. A variety of animals provide leather: crocodiles, kangaroos, dogs and cows to name a few. Did you know that leather pouches were once used to store water? It is still used to make bags and other containers. Cotton is made of cellulose and can be stretched to neat pieces of fabric.

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Does human skin share any similarity with that of animals?

          Human skin appears very different from that of animals. Think of an elephant’s skin and then take a look at yours. They are as different as chalk and cheese, isn’t it? Even all animals do not have the same texture of skin. But, they have one thing in common; both human and animal skin is made of a protein called collagen.

          Collagen has a fibre-like structure. It forms an elastic layer below the skin which makes it smooth and supple. Collagen present in animal skin can be made into leather by a process called tanning during which, the skin will be cross linked. This modification makes it strong and durable.

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Why was the tusk of a walrus used to make jewellery?

          The walrus is a sea animal with a not-so-pleasant appearance. But they were hunted for their tusks, meat and skin. They have long ivory tusks just like elephants.

          The tusk of a walrus is soft enough to be carved to any shape, but sturdy enough to stay for a really long time. Because of this, walrus tusks were used to make jewellery in the past. Wonder what the tusk is made of? The ivory tusk of a walrus is made of a protein, a polymer which makes our hair and fingernails. The protein provides longevity and softness lo the tusk. Now, we have a lot of alternatives for jewellery and this poor creature is largely spared.

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Which polymer is present in the outer shell of crabs?

          The hard outer shells of crabs and lobsters are made of a polymer called chitin. Chitin is a polysaccharide which is hard and insoluble, but somehow flexible. It is found in the shells of shrimps and other crustaceans as well.

          Have you observed the shells of crabs? Does it get wet? Don’t be surprised to learn that chitin is waterproof. It is non-toxic, biodegradable and structurally similar to cellulose. However, it is a major source of surface pollution in coastal areas.

           Chitin is a promising biomaterial and a considerable amount of research about chitin is being conducted worldwide now. Researchers have tried hard to synthesize synthetic polymers with the same properties as chitin. Thanks to their efforts, it is commercially produced in some parts of the world today.

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Do whales have polymers in them?

          The aquatic world is a vast repository of natural polymers. Aquatic mammals have several proteins in them. Whales are no exception. The teeth of a whale are rich in baleen, a natural polymer.

          Baleen is made up of keratin, a type of protein. It is strong, durable and flexible. Keratin is generally of two types – hard and soft. Hard keratin is usually found in human fingernails, hair and claws of birds. Soft keratin is found in whale bone. Another prominent polymer obtained from a whale is leather. Leather is processed from its skin and has a variety of applications.

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Is there anything common between cellulose and starch?

           Starch and cellulose are very different from each other, but they share a striking similarity. Both are made of glucose monomers and hence called polysaccharides. Though made of glucose, both are bonded in different ways which give them different properties.

         Starch dissolves in water while cellulose doesn’t. Cotton is made up of cellulose; it has a crystalline structure and stretches out. Just imagine what would happen to our cotton clothes if cellulose could be dissolved in water? It would disappear in the very first wash! Cellulose and its derivatives are widely used to make clothing and other things like paper, while starch is used for food.

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Can we eat polymers?

          Yes, there are polymers that can be eaten. In fact, we consume a lot of polymers daily without even thinking about it. Don’t be surprised. Think of a chicken burger. Chicken contains a lot of protein and the bun contains starch. Both protein and starch are polymers.

          Proteins make up a major chunk of our body; it constitutes organs, muscles and fingernails. Milk, eggs, meat, seeds and nuts are protein rich foods. Starch is a polysaccharide with high molecular weight. Our body breaks down starch into glucose which gives us energy to work and play. In short, polymers give us energy to do everything. Foods like corn, potatoes and bread are rich in starch.

          Cellulose is also present in vegetables and grains, but we cannot digest it.

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Is life possible without polymers?

          You won’t be wrong if you say that life on Earth won’t be possible without polymers. Wonder why? Look at what our body is made of. Our body contains proteins, peptides and enzymes. These wouldn’t be possible if not for RNA, which is a polymer. RNA makes possible the synthesis of proteins and enzymes. Our hair is made of keratin, a protein and skin is constituted of polymerized collagen. DNA contains the basic programming of our body. DNA too is a polymer.

          Polymers make up not only the human body, but also plants and animals. A rhino’s horn is made of keratin while cell walls of plants are made of cellulose. The list does not end here. Several other polymers like chitin are found in organisms like crabs. Let us now take a close look at different natured polymers.

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What is special about biodegradable polymers?

           Biodegradable polymers are decomposed by microorganisms like bacteria. While decomposing, they produce natural by-products like gases, water and inorganic salts. Wood is a natural biodegradable polymer.

          Are natural polymers the only biodegradable ones? Not really. Some synthetic polymers are also biodegradable and they do not have any adverse effect on the environment. Remember vitamin E capsules? The shell of the capsule is made of a biodegradable polymer. Surgical bands and sutures also make use of biodegradable polymers. Polylactic acid used for packaging is yet another example. 

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Why are some polymers stable at high temperatures?

          Think of hospital equipment that is used for processes like sterilization. Any idea about the kind of polymers used in them as they need to withstand high temperature?

          Some polymers are stable at very high temperatures. These polymers have strong force of attraction between the molecules. They also have special network structure. Some additives are added to some of these polymers which enhance their thermal resistance.

          These polymers are usually known as high temperature polymers and can withstand a service temperature greater than 150 degrees. They can even withstand temperatures higher than 250 degrees for a short span. They are very expensive and hence are used in small amounts.

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How are molecules arranged in a polymer?

         

          Polymers can be arranged in two formations. If the molecules do not have a long-range order, the polymer chain has an amorphous arrangement. Amorphous polymers are generally transparent.

          Contact lenses, plastic windows and transparent food wraps are generally made of amorphous polymers.

          What about polymers those are not transparent? Translucent and opaque polymers have crystalline arrangement of molecules. Here, the atoms and ions are arranged in definite patterns. Generally, the amount of light that can pass through a polymer decreases with increasing amounts of crystallinity. So, the opaqueness of a polymer is an indicator of the degree of crystallinity.

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How is an organic polymer different from an inorganic polymer?

                    Think of the human body. What is it that gives us our shape? The skeleton of course. Without the skeleton, we would be a lump of flesh. Similarly all polymers have a skeleton which gives them their structure. Organic polymers have a carbon backbone. Their monomers are simple organic compounds.

           On the other hand, the backbone of an inorganic polymer is constituted by elements other than carbon, say phosphorous or sulphur. Most of the organic polymers have simple structures while inorganic polymers are highly branched with complex structures.

           Though they have carbon bonding, graphite and diamond are inorganic polymers. This is because they are constituted by carbon atoms alone which crosslink to give their structure.

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Is nylon a fibre?

           Nylon is a synthetic fibre which is commonly used in the textile industry. The word fibre will give you an image of interlinked threads. Synthetic fibres are man-made fibres that are derived from several chemical processes. They can be easily woven because of their thread-like nature. The force of attraction between the monomers of a fibre is very strong; the monomers crosslink to form a strong hydrogen bond.

          Nylon is also used for making fishing nets, ropes and parachutes because it is strong and long lasting. Like nylon, polyester and rayon too are synthetic fibres. They are non-toxic substances and can be dyed.

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How is a thermosetting plastic different from a thermoplastic?

          Unlike thermoplastics, thermosetting plastics cannot be remoulded or reshaped. It assumes a permanent hard shape once heated.

          Initially, this is a liquid or a soft solid. Chemical reactions take place when it is heated and the long polymer chains crosslink to form a three dimensional structure. You might have bright coloured melamine dinnerware at home.  Melamine is a thermosetting plastic. Bakelite, which is used for insulating electric wires, also belongs to this category.

          Thermoplastics can be remelted quickly, but thermosetting plastics can withstand high temperatures. It cannot be recycled for the same reason.

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Which material is used for making plastic bottles?

           Do you know how a plastic bottle is made? At first, the raw material used for making the bottle is heated and blown. It is then passed through another mould which gives it shape.

          The production of a plastic bottle is possible because the raw material can be moulded into any shape at a certain temperature. It then solidifies after cooling. Polymers of this kind are known as thermoplastics. Thermoplastics soften up on heating and harden when they are allowed to cool down They can be melted and recast into any possible shape. PET bottles and toys are has usually made of thermoplastics.

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Why does a rubber band regain its original shape after it is stretched?

          You might have tried stretching a rubber band or squeezed a rubber toy. Have you noticed that they regain their original shape once they are released? This is possible because they are elastomers.

          Elastomers are rubber-like solid polymers with elastic properties. That is, they can be easily stretched and can regain their original shape no matter how much you squeeze or stretch them. The force of attraction between the molecules of an elastomer is weak. Remember vulcanized rubber that we discussed earlier? That too is an elastomer. Vulcanized rubber has a cross linked chain which is helps it remain its original form.

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How is an addition polymer different from a condensation polymer?

          Addition polymers are formed by the repeated addition of monomers. No by-products are formed in this linkage.

          Polyethene which is used for making plastic carry bags and toys are formed by the process of addition. The monomers either contain a double bond or have a ring structure containing three to seven atoms.

          On the other hand, condensation polymers are formed when monomers condense while bonding. By-products are formed in this reaction and small molecules like water are lost. Most of the natural polymers are synthesized using this process.

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How are polymers classified based on their structure?

          Properties of a polymer depend on how monomers are linked together. There are three basic structures for polymers – linear, branched and cross-linked.

          Linear polymer is the simplest polymer. It has a long, straight chain with identical linkage. PVC is a liner polymer. Teflon is another linear polymer made from tetrafluoroethylene. Branched chain polymers have a long, straight chain with branches of different lengths originating at random points. These branches are known as side chains and can have different lengths. Low-density polyethene (LDPE) used in plastic bags is a branched chain polymer.

          There is another category known as cross-linked polymers. It has a three dimensional network of monomers with long chains of linear or branched polymers.

          A cross linked polymer has strong covalent bonding that attracts other polymer chains and creates a more stable material. It is also known as network polymer. Bakelite which is used to make sockets is a network polymer.

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How can we classify polymers?

          We have a tendency to classify everything around us. Similar things are often grouped together for the ease of understanding. Polymers too can be grouped based on different criteria.

          We already discussed natural, synthetic and semi-synthetic polymers. This classification is based on their source. Are there other possible ways to classify them? Indeed yes!

         Polymers can be clubbed together based on their structure, molecular forces and type of polymerization. Look at the diagram to get a clear picture of this.

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Why is the World War II era a significant period in the history of polymers?

          Polymer production emerged as a strong commercial industry during the Second World War. There was a scar-city of natural materials like rubber and silk during the war years, which created a high demand for them.

          The increasing demand created a crisis which further led to an increase in the production of synthetic substances like nylon and synthetic rubber. Moreover, the scarce natural resources needed to be preserved. This made the synthetic alternatives a priority and plastics made it possible!

          The increase in the production of synthetic polymers touched almost all aspects of daily life. Nylon was used for making parachutes, body armours, ropes and helmet liners. It caused a huge change in the fashion industry as well. Rayon, the new synthetic material discovered in the 1930s solved the crisis in natural fabrics and was widely used to make clothing.

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Who is known as the father of polymer chemistry?

          On account of his contributions to polymer science education and research, Herman Francis Mark is known as the father of polymer chemistry. He worked on polymers for almost 75 years and produced more than 600 research papers and 40 books about polymer chemistry. A huge number indeed!

          Mark studied molecular structures of natural textile fibres like silk and wool. He applied modern physics to the study of large molecules; his work on molecular structures using X-Ray diffraction provided sufficient evidence for macromolecular theory of polymer structure.

         Mark’s interests included the mechanical properties of polymers. He led the commercial production of polystyrene, a tough colourless plastic. He is also credited for developing several theories and even an equation!

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Why is Hermann Staudinger an important figure in polymer chemistry?

          Herman Staudinger was not the first chemist to work with polymers. But his significant contributions laid the foundations to diverse applications of polymers.

          Staudinger was a professor in organic chemistry at Zurich when he proposed some of the pioneering theories on polymer structures of fibres and plastics.

          In the 1920s, he found out that rubber has a high molecular weight. He also presented a paper showing several reactions capable of forming structures high molecular weight.

          Staudinger explained how smaller units combine to form a large structure. He called the process polymerization. Before that, polymers were thought of as aggregates of molecules and this idea was based on Thomas Graham’s work. His studies on biological macro-molecules led to a lot of later discoveries of commercial importance.

          Staudinger’s ideas were criticized heavily by other chemists of his time, but were finally accepted by the 1950s. In 1953, he was awarded the Nobel Prize in chemistry for his contributions in understanding macromolecular chemistry.

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What were some of the pioneering discoveries in polymer chemistry?

           Before chemists formulated the basic idea of polymers, Mexicans knew some ways to use polymers. They knew how to modify rubber. Several substances were added to natural rubber. These additives modified and enhanced its properties and were used to make a range of products like bouncing balls.

          Henri Braconnot’s work is the first modern work associated with polymers. In the 1830s, Braconnot along with the help of some others developed celluloid and cellulose acetate, derivatives of cellulose.

          Later in the 1840s, vulcanization of rubber entered the scene which created a huge change in the industry. It was discovered that adding sulphur to natural rubber will make it stable, flexible and prevent stickiness. This led to the production of many useful products like waterproof articles. Vulcanized rubber is undoubtedly the first commercially successful polymer.

          By the 1880s, artificial fibres entered the scene. Hilaire de Chardonnet started the first artificial fibre plant in 1884. It was based on regenerated cellulose which worked as a substitute for silk. Bakelite, the first synthetic plastic was discovered only after more than twenty years in 1907.

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What is polymer degradation?

          Have you observed PVC pipes that are attached to the water tank? You might have noticed that the pipes exposed to sunlight lose colour after a while. These pipes will also lose their strength and become brittle. PVC pipes lose hydrogen chloride gas when exposed to high temperatures.

          Polymers undergo a change their properties like colour, shape or molecular weight when they are exposed to one or more environmental factors like heat, light or chemicals. This change is known as polymer degradation. It is usually undesirable. However, it is useful in recycling polymer waste. Biodegradable plastics are degraded with the help of microorganisms.

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How are monomers combined?

            We have been talking about polymers a lot. But how are they synthesized? A polymer is made by combining monomers to form a long chain and for this; monomers react and combine in a process called polymerization.

            A monomer has the capacity to form chemical bonds with at least two other monomer molecules. Nucleic acid is a natural polymer which is formed when nucleotide monomers bond. How does a PVC pipe take shape? Vinyl chloride is the monomer that reacts in a certain fashion to form polyvinyl chloride (PVC).

            Polymers are formed either by repeated addition or condensation of monomers. Accordingly, polymerization is generally of two types which we will talk about later in detail.

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What are the characteristics of polymers?

          Polymers can be processed in various ways. The characteristics of polymers depend on the chemical bonding between the monomers and the process used to make them. However, polymers have some common attributes.

         Generally, all polymers have long chains consisting of hundreds of monomers. Most polymers show a high resistance to chemicals. Look at the cleaning materials used in your house. When it comes in contact with your skin or eyes, it can cause rashes or itching. But they are safely packed in plastic bottles and the packaging remains unaffected by its contents.

          They resist heat and that’s why, most of the handles of cook-wares are made of plastics. They are good electrical insulators as well. Remember Bakelite, which is used to insulate electric wires. All electric appliances, cords and wirings are covered with polymeric materials.

          Polymers are light in weight, but have significant strength and their inherent properties can be enhanced by using a range of additives. They do not generally melt; because of their structure, they change from crystalline to a semi-crystalline form when heated.

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How are synthetic polymers made?

          Polymers are made by bonding monomers. The process of formation of a polymer is known as polymerization and each polymer has a different combination of sub units.

         Many of the polymers are made by breaking up hydrocarbons. Hydrocarbons are heated up to break the large molecules into smaller ones. This is done in the presence of a catalyst, a material that speeds up the chemical reaction.

         To understand more about the process, let’s look at how plastic is made. To make plastic, natural gases or crude oil are broken down into monomers such as ethylene or butane. These monomers are then combined to form polymers in a chemical reaction. The properties of polymers depend on how the monomers are being bonded.

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Can we chemically modify natural polymers?

          Natural polymers can be modified by chemical treatment.

          The product obtained after the modification is known as a semi-synthetic polymer. A new polymer is synthesized out of a naturally occurring one and hence the name!

          Vulcanized rubber is a semi-synthetic polymer. Rubber in its natural form is not thermally stable. It becomes very hard when it is cold and melts down in heat. But, when treated with sulphur, rubber achieves thermal stability and becomes flexible and can be used to make a range of useful products. This chemical treatment of rubber is known as vulcanization.

           Similarly, many other natural polymers can be modified into semi-synthetic polymers with desirable properties.

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