Category Chemistry

Why is salt soluble in water but not in oil?

     The solubility of a substance depends on the nature of bonding in both the solute and the solvent. Salt is an ionic substance; that is, its atoms are held together by opposite electrical charges. Water molecule also has electrical charges – the hydrogen atoms are positively charged and the oxygen atom negatively charged. When salt is put in water the charges on the water molecule pull the oppositely charged atoms in salt apart, thus dissolving it. Oil molecules, on the other hand, do not carry any charge and so does not have any effect on the ionic bonds in salt when put in it. As a result, salt does not dissolve in oil.

                                    

Why is difficult to tie a knot in a silk lace?

            A knot in a lace is held together by the friction between the surfaces of the lace. Greater the friction more stable the knot will be. Since there is enough friction between cotton fibres in a lace made of cotton, it is quite easy to tie a knot. But silk being a smooth fibre, a knot tied with a silk lace becomes loose and opens up easily due to lack of friction between the fibres.

                                    

Why do bubbles show rainbow colours?

   Bubbles are balls of thin soap films. They show rainbow colours because the light falling on them undergoes what is known as interference. Light travels in the form of waves which have troughs and peaks at regular intervals. For instance, one wavelength of a light-wave has one trough and one peak. When light falls on a soap bubble it is reflected from both the upper and lower surfaces of the film. Thus, there are two waves of reflected light emerging out of surfaces of the soap bubble. If the distance between the two surfaces of the film is less than one wavelength of light, the two reflected waves are so close that interference occurs. The peaks of the two waves may add up and become a bigger peak. Or the trough of one wave may fall with the peak of the other thus cancelling its effect. As the seven component colours of white light have different wavelengths, the adding or cancelling effect of interference is not the same on all of them. In other words, some colours become brighter and some duller. Thus a viewer sees a mixture of rainbow colours instead of the white light emerge from the soap bubble.

                                    

Why do coloured soaps produce white bubbles?

Foam or lather is nothing but a large collection of small soap bubbles. A soap bubble is, in turn, a very thin film of soap solution enclosing some in air. Because of the low surface tension of soap solution, the film can stretch and spread and form innumerable bubbles with a very large total surface area. Because of this, whatever slight tint present in the thin film of the coloured soap solution gets subdued. Although a soap film is more or less transparent, the lather or foam looks white because the light striking this large collection of bubbles gets scattered. That is why all kinds of foam look white.

                                    

Why does ice melt when subjected to pressure?

  One of the laws of fusion is that the melting point of substances which expand on freezing is lowered by the increase of pressure, while it is raised in the case of those which contract on solidification. Ice belongs to the first category of substances, that is, it expands on freezing. Ice has an open structure which collapses when subjected to pressure, producing water which occupies lesser volume. That is why ice melts when subjected to pressure.

Why does the surface of boiling milk rise?

            Milk is a fine suspension of fat and protein globules in a watery liquid containing milk sugar (lactose) and other dissolved substances. Normally the fat is dispersed uniformly in the form of fine droplets and hence remains as an emulsion. But when milk is heated these fine droplets tend to raise up and at temperature of about  form a thick layer of cream on the surface. When milk comes to boiling, bubbles of steam formed at the bottom of the vessel rise up and force the thick creamy layer upwards causing the milk to spill.