Category Chemistry

Crude oil is a thick, black liquid found deep under the Earth’s surface. It was formed millions of years ago from the bodies of tiny animals and plants which lived in the sea. Crude oil is a mixture of many very useful chemicals.

Crude oil is pumped up to the Earth’s surface and is piped to a refinery. Here the different liquids are separated from each other. Some of the liquids, such as petrol and paraffin, can be used as fuels. Others are changed chemically to produce compounds, such as plastics and waxes. Chemicals that come from oil are contained in many of the things we use every day, such as plastic bags and bottles, drain pipes, and some window frames and carpets.

Each liquid chemical boils at a different temperature. The temperature at which it boils is called its ‘boiling point’. When crude oil is heated at the refinery, its temperature slowly rises. The liquid with the lowest boiling point is the first one to boil and form a gas.

This rises upwards, then cools back to a liquid and is collected. As the heating continues, the liquids are separated and collected one by one. The last liquid to be collected is the one with the highest boiling point. This process of separation is called ‘distillation’.

Some chemicals are acids or alkalis. Vinegar, lemon juice and sour milk are all weak acids. They all have a similar sharp, sour taste. Oven cleaner, washing soda and toothpaste are all alkalis. Alkalis taste bitter and feel soapy.

Our stomachs contain hydrochloric acid. This acid kills some of the bacteria in our food and helps us to digest our meals. Too much stomach acid causes indigestion. Medicines used to cure stomach pains are often alkalis. When you mix an alkali with an acid, you make a ‘neutral’ solution — neither acidic nor alkaline. Many plants thrive in a soil which is not very acid, so farmers may add lime to the soil. Lime (an alkali) ‘neutralizes’ acidic soil.

Indicators

An ‘indicator’, such as litmus, is a substance that changes colour when it is mixed with an acid or an alkali.

When litmus paper is dipped into lemon juice, it turns red. Alkaline stomach medicine turns it blue. When the acid and the alkali are mixed, a neutral solution is formed which does not colour the litmus.

Car batteries contain a very strong acid solution. Never touch a car battery with bare fingers.

Farmers and gardeners use an alkali – lime – to neutralize acidic soil before planting.

One way of separating chemicals is to use a ‘filter’. A face mask is a type of filter. It is made of material that is full of tiny holes. Air can pass through these holes but particles of dust or paint are too big and get trapped on the outside of the mask.

A filter cannot separate salt from a salt solution. The sodium and chlorine atoms and the water molecules which form a salt solution are small enough to pass through the holes of any filter. If the solution is warmed, the water begins to change into vapour and eventually only salt is left behind. We call this process ‘evaporation’. Stalagmites form by evaporation.

Chromatography

There are three primary colours — red, blue and yellow. Most inks are made by mixing two or more of these colours. To separate ink, a process called chromatography is used. To try this yourself, draw a small circle on blotting paper using a water-based pen. Then put a drop of water on top of the circle. As the water spreads through the blotting paper, it carries the chemicals at different speeds and separates the colours.

Electrolysis

Electrolysis is a process used to separate elements from compounds. An electrical current from a battery is passed through a liquid — called the electrolyte. Some molecules in the electrolyte are positively charged and others are negatively charged. Positively charged particles are attracted to the negative electrode. Negatively charged particles are attracted to the positive electrode. The liquid begins to separate. Electrolysis can be used to purify metals.

A Face mask separates chemicals by preventing large particles from passing through the holes.

We have seen how to separate salt from a salt solution. If you look at salt under a microscope, you can see that each grain of salt is a perfect cube. The cubes form naturally as the salt comes out of solution. They are called salt ‘crystals’. All salt crystals are the same shape, but they may be different sizes.

Many chemicals form crystals. Sugar makes crystals and so does water when it turns to frost or snow. Each type of crystal has its own shape. Most rocks are made of crystals of chemical compounds called ‘minerals’. Granite is made up of crystals of ‘quartz’, ‘feldspar’ and ‘mica’. Crystals of diamond or emerald may be made into jewellery.

Salt crystals

Salt is made up of an equal number of sodium and chlorine atoms. When salt is in solution, these atoms are far apart. But as the water evaporates, the atoms get closer together. They always arrange themselves in the same way. This arrangement, called a ‘crystal lattice’, gives the salt its cubic shape.

Carbon

Carbon is an element: it is made up only of carbon atoms. But these atoms can arrange themselves in a number of ways to form several different types of carbon crystals. For example, charcoal is a soft black substance which can be used for drawing or may be burnt as a fuel; graphite is harder and is used to make the ‘lead’ in pencils. Surprisingly, diamonds are also pure carbon! Unlike charcoal and graphite, diamonds are extremely rare. They are used to make highly priced jewellery, and they also have industrial uses. Diamond is the hardest substance known and can be shaped to make cutting tools. Diamonds are also crystals of carbon. They are cut in a particular way to make them sparkle.

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Salt ‘disappears’ in water. But a taste of the liquid tells you that the salt is still there. So what has happened to the salt? When salt is mixed with water, the sodium and chlorine atoms break away from each other and move freely in the water. Gradually, the sodium and chlorine atoms and the water molecules are mixed up evenly. The liquid is called a salt ‘solution’. The salt has ‘dissolved’.

Many substances dissolve in water. Water is a good ‘solvent’. Carbon dioxide gas dissolves in water and makes it fizzy. Some substances dissolve in different solvents — paint dissolves in white spirit. Detergents ‘help’ water to dissolve oil.

Drops of oil floating on water will rush away from a drop of detergent added to the water. This is because detergent causes the surface of the water to change and the oil starts to dissolve.

Diffusion

If orange juice is poured down a straw into a glass of water, an orange patch forms in the middle of the water. The molecules of the water and the orange juice are moving all the time. Eventually, the orange molecules spread evenly throughout the water and the solution looks pale orange all over. This spreading of molecules is called ‘diffusion’.

Sea water is a massive solution of salt and water.

Oil-based paint does not dissolve in water, but it will dissolve in a solvent called white spirit.

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When water changes its state, its molecules are still made of hydrogen and oxygen — the chemical itself has not changed. When elements combine to make a compound, new molecules are formed. This is a ‘chemical change’.

We see examples of compounds forming every day. Most metals combine with chemicals in the air. Copper roofs slowly turn green as the copper combines with water and oxygen to form a new compound. An iron nail left outside soon starts to turn brown. The iron has reacted with water and oxygen in the air to form ‘rust’. Cars are made of several metals including iron. They have to be coated in paint to try to prevent them from rusting.

Baking a cake

When you bake a sponge cake, one of the ingredients used is baking powder. As it is heated in the oven, the baking powder breaks down into different chemicals. One of these is a gas — carbon dioxide. The bubbles of carbon dioxide throughout the sponge make it light and fluffy. The baked sponge is now a new mixture of many different compounds.

Copper roofs slowly turn green as the copper combines with oxygen to form a new compound.

Iron bridges need to be coated with chemicals to prevent them from rusting.

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